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Honestly, I think that it is your job as a friend to offer support and care, I wouldn't be telling her what to do, ie. that she should leave her husband. I would be focusing on talking to her about whether she wants to stay in her existing relationship and not so much leaving to enter a new one.
There are other ways of talking her without say that she should leave outright, like, "you don't deserve to be treated badly", "do you want to stay in your marriage?" More like probing questions to help her decide what she wants without you telling her what you think she should do. It might come back to bite you later otherwise.
I think that if they really are soul mates and both of them want to be together then they will make it happen. But that's just my opinion, you don't have to take it as gospel :p