Not really. I mean, it may help you to conceive ever, ever so slightly, by making sure your body is healthy, but I don't think they will affect tour month to month chances of conception. I was on them for 1 and a half years of the two years TTC. I think if you are fertile, then you are fertile, there isnt a lot a multivitamin will do to change that, kwim?
The pregnancy and BF vitamins are to prepare your body for both of those things (ensuring your body is getting lots of nutrients even if you're not eating well, due to MS, sleep deprivation, etc) and they're not designed to help you conceive.
If you want conception help in the form of a vitamin, Blackmores do a Conceive Well tablet. I agree with PZ though, you can do a bit to help your fertility but I don't think a vitamin is really the answer.
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