We use a couple of teaspoons of bicarb or ecostore. You can use tea tree oil etc in the rinse or fabric softener compartments as antibacterial/antifungal but also helps with the ammonia smell.
Washing powders with whiteners in them are bad for the nappies but I think only fabric softeners and too much washing powder will effect absorbancy.
Have just used water and bicarb in the past. Apparently the enzymes/whiteners in modern powders aren't great for nappies. I've used cloth for over 6years now and initially nothing was ever mentioned about the type or amount of powder. I used to use regular and have never had troubles with any nappies being ruined. Did have to strip wash a bit more often due to buildup, but that was no biggie.
Too much detergent can block up your nappies though and make them not as absorbent.
I have also used Charlies soap which was expensive and horrendous! Caused all sorts of yuck burns on her.
I use eco store too. You want powder that is phosphate free, I think.
You can also use a brand called "rockin green". Ive never tried it, but its very popular and sold on most cloth nsppy sites and in the nappy store I go to.
I use 2 squirts of Method laundry liquid. Lasts for yonks! And yep, pop your oils (sometimes I use vinegar) in the fabric softener compartment.
I also like to use an extra rinse cycle for the nappies.
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