I used to use barrier cream around my hairline (ok over half my face because I'm seriously bad with hair dye) - eucalyptus or tea-tree oil will get it off but make sure you don't have a reaction to it first.
Yes to the cigarette ash thing, it does work (although it is a bit icky lol). Next time you dye, keep a pack of baby wipes at the ready so that you can wipe up any smears before it stains your skin, that's what I do with mine and DH's hair
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