This general chatter thread is fairly new, and there was an informal one before this one was created, where me and a couple of others talk about the early days of EC'ing. Just have a look through the threads on ECing here to find them
Ingrid Bauer's book Natural Infant Hygiene is a most excellent start for the journey, as well as subscribing to Tribal Baby's website for the free info and tips.
Above all, it's about enhancing your relationship with your child, not perfecting clean toileting It's very rewarding when you do 'get it right', and it's not the be all and end all to catch every single motion.