My big thing with homeschooling is that I think it would add extra stress on our relationship. LOL, it's already hard enough getting them to do what I ask just for family life; I can't imagine adding schoolwork on top.
I've know several people who have done it, very successfully. They plan group times for the kids, usually with other homeschoolers, and often send them to school for high school, or year 10-11 on.
Also, LOL, while I love the kids dearly, I also love having that quiet time at home while they are away at school...!
I would do it if I had to, but I don't want to